Il Polo Solare Organico della Regione Lazio (CHOSE) è nato nel 2006 dalla volontà della Regione Lazio e dell'Università degli Studi di Roma Tor Vergata di creare un centro di eccellenza nel settore del fotovoltaico di nuova generazione.
Simon Ternes
Post Doctoral Research Fellow
C.H.O.S.E.
c/o Casale 11
University of Rome "Tor Vergata"
Viale Pietro Gismondi s.n.c. - 00133 Rome - Italy
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Simon Ternes obtained his Master's degree in Physics from the University of Heidelberg in Germany (2017), where he worked on bar-coating of perovskite solar cells in Prof. Yana Vaynzof’s group. He completed his PhD thesis ‘In Situ Characterization and Modelling of Drying Dynamics for Scalable Printing of Hybrid Perovskite Photovoltaics’ at Karlsruhe Institute of Technology (2022) under the supervision of Prof. Wilhelm Schabel, Prof. Bryce S. Richards and T.T. Prof. Ulrich W. Paetzold. One year later, Simon was granted the Marie Skłodowska-Curie fellowship, ‘An intelligent perovskite solution printing line’, in cooperation with Prof. Alessio Gagliardi (Technical University of Munich, Germany) and Prof. Aldo Di Carlo (University of Tor Vergata, Italy) which he conducts at CHOSE since 2023.
The work of Simon Ternes focuses on in situ characterization and advanced modelling concepts for enhancing process control of large-scale perovskite printing. In particular, he is interested in non-invasive, rapid optical haracterization techniques such as reflectance, absorption and photoluminescence for developing data-intensive models of perovskite drying and crystallization processes to address the challenges of scaling and reproducing hybrid perovskite solar cell fabrication.
• Simon Ternes, In Situ Characterization and Modelling of Drying Dynamics for Scalable Printing of Hybrid Perovskite Photovoltaics. Karlsruhe: KIT Scientific Publishing. ISBN: 978-3-7315-1255-4 DOI: https://doi.org/10.5445/KSP/1000152603
• Simon Ternes, Jonas Mohacsi, Nico Lüdtke, H. Minh Pham, Meriç Arslan, Philip Scharfer, Wilhelm Schabel, Bryce S. Richards, and Ulrich W. Paetzold*, Drying and Coating of Perovskite Thin-Films: How to Control the Thin-Film Morphology in Scalable Dynamic Coating Systems, ACS Appl. Mater. Interfaces 2022, 14, 9, 11300–11312, https://pubs.acs.org/doi/abs/10.1021/acsami.1c22363
• Simon Ternes, Felix Laufer, Philip Scharfer, Wilhelm Schabel, Bryce S. Richards, Ian A. Howard, Ulrich W. Paetzold, Correlative In Situ Multichannel Imaging for Large-Area Monitoring of Morphology Formation in Solution-Processed Perovskite Layers, Sol. RRL, 6: 2100353, https://onlinelibrary.wiley.com/doi/full/10.1002/solr.202100353
• Simon Ternes, Tobias Börnhorst, Jonas A. Schwenzer, Ihteaz M. Hossain, Tobias Abzieher, Waldemar Mehlmann, Uli Lemmer, Philip Scharfer, Wilhelm Schabel, Bryce S. Richards, Ulrich W. Paetzold, Drying Dynamics of Solution-Processed Perovskite Thin-Film Photovoltaics: In Situ Characterization, Modeling, and Process Control, Adv. Energy Mater. 2019, 9, 1901581, https://onlinelibrary.wiley.com/doi/full/10.1002/aenm.201901581.
• Paul Fassl, Simon Ternes, Vincent Lami, Yuriy Zakharko, Daniel Heimfarth, Paul E. Hopkinson, Fabian Paulus, Alexander D. Taylor, Jana Zaumseil, and Yana Vaynzof Effect of Crystal Grain Orientation on the Rate of Ionic Transport in Perovskite Polycrystalline Thin Films, ACS Appl. Mater. Interfaces 2019, 11, 2490-2499, https://pubs.acs.org/doi/10.1021/acsami.8b16460
Emanuele Calabrò
Post Doctoral Research Fellow
C.H.O.S.E.
c/o Casale 11
University of Rome "Tor Vergata"
Viale Pietro Gismondi s.n.c. - 00133 Rome - Italy
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Emanuele Calabrò was born on 8th August of 1987 in Rome. He obtained his MSc in “Material Science and Technology” at Tor Vergata University in 2015, with a thesis based on the application of Bragg Gratings applied for Perovskite Solar Cells (PSCs) and Dye Sensitized Solar Cells (DSSCs). He performed his PhD in “Electronic Engineering” under the supervision of Prof. Aldo Di Carlo. His topic was the optimization and scaling-up of Low-T based planar Perovskite Solar Cells and Modules followed by the stability analysis of the as fabricated devices. Currently is a Postdoctoral Fellow at C.H.O.S.E. labs under the supervision of Prof. Andrea Reale.
The research activity of Emanuele Calabrò was based on the development and optimization of highly efficient hybrid-organic perovskite solar cells and modules (PSCs & PSMs) based on a low-T approach. The results obtained due the incorporation of a SnO2 layer as ETL led the achievement of high performances. The easy scale-up of the planar structure, coupled with an optimized selective laser system ablation, permitted the fabrication of PSMs up to 50 cm2 with high aspect and ratio high-performance. Furthermore, the perovskite doping with innovative materials permits to increase the stability of the photovoltaic devices under thermal stress. His research is currently focused on the "COPPER" Project funded by the Lazio and Lazio Innova Region. The aim of the project is the evaluation of the impact of semitransparent organic PV with tunable colors applied to agrivoltaic systems and how it affects the growing plants.
1) Emanuele Calabrò, Fabio Matteocci, Alessandro Lorenzo Palma, Luigi Vesce, Babak Taheri, Laura Carlini, Igor Pis, Silvia Nappini, Janardan Dagar, Chiara Battocchio, Thomas M. Brown, Aldo Di Carlo; Low Temperature, Solution processed Perovskite solar cell and modules with an Aperture Area efficiency exceeding 11%, Solar Energy Materials & Solar Cells, 185, 136-145, (2018).
DOI: 10.1016/j.solmat.2018.05.001
2) L. Palma, F. Matteocci, A. Agresti, S. Pescetelli, E. Calabrò, L. Vesce, S. Christiansen, M. Schmidt, A. Di Carlo; Laser-Patterning Engineering for Perovskite Solar Modules with 95% Aperture Ratio, IEEE Journal of Photovoltaics, 99, 1 – 7, (2017).
DOI: 10.1109/JPHOTOV.2017.2732223
3) Janardan Dagar , Sergio Castro-Hermosa, Matteo Gasbarri, Alessandro L. Palma, Lucio Cinà, Fabio Matteocci, Emanuele Calabrò, Aldo Di Carlo, Thomas M. Brown; Low Temperature Solution-Processed Flexible Perovskite Module and Solar Cell Based on SnO2/meso-TiO2 Scaffold Electron Transport Layer, Nano Research, 5, 11, 2669-2681, (2018).
DOI: 10.1007/s12274-017-1896-5
4) Leyla Najafi, Babak Taheri, Beatriz Martín-García, Sebastiano Bellani, Diego Di Girolamo, Antonio Agresti, Reinier Oropesa-Nuñez, Sara Pescetelli, Luigi Vesce, Emanuele Calabrò, Mirko Prato, Antonio E Del Rio Castillo, Aldo Di Carlo, Francesco Bonaccorso; MoS2 Quantum Dot/Graphene Hybrids for Advanced Interface Engineering of a CH3NH3PbI3 Perovskite Solar Cell with an efficiency of over 20%, ACS Nano, (2018)
5) Aleksandra Furasova, Emanuele Calabró, Enrico Lamanna, Ekaterina Tiguntseva, Elena Ushakova, Eugene Ubyivovk, Vladimir Mikhailovskii, Anvar Zakhidov, Sergey Makarov, Aldo Di Carlo; Resonant Silicon Nanoparticles for Enhanced Light Harvesting in Halide Perovskite Solar Cells, Advanced Optical Materials, 1800576, (2018).
6) Diego Di Girolamo, Fabio Matteocci, Enrico Lamanna, Emanuele Calabrò, Aldo Di Carlo, Danilo Dini; Inverted perovskite solar cells with transparent hole transporting layer based on semiconducting nickel oxide, AIP Conference Proceeding 1990,020011 (2018).
7) Alberti Alessandra, Smecca Emanuele, Sanzaro Salvatore, Bongiorno Corrado, Giannazzo Filippo, Mannino Giovanni, La Magna Antonino, Liu Maning, Vivo Paola, Listorti Andrea, Calabrò Emanuele, Matteocci Fabio, Di Carlo Aldo; Nano-structured TiO2 grown by low-temperature reactive sputtering for planar perovskite solar cells, ACS Applied Energy Materials, 2019, 2, 9, 6218-6229.
8) Babak Taheri, Emanuele Calabrò, Fabio Matteocci, Diego Di Girolamo, Giorgio Cardone, Aldo Di Carlo, Francesca Brunetti; Automated scalable Spray coating of SnO2 for the fabrication of low temperature perovskite solar cells and modules, EnergyTechnology, 2020, 1901284.
9) Enrico Lamanna, Fabio Matteocci, Emanuele Calabrò, Luca Serenelli, Enrico Salza, Luca Martini, Francesca Menchini, Massimo Izzi, Antonio Agresti, Sara Pescetelli, Sebastiano Bellani, Antonio Esau Del Rio Castillo, Francesco Bonaccorso, Mario Tucci, Aldo Di Carlo; Mechanically stacked, two-terminale graphene-based perovskite/silicon tandem solar cell with stabilized efficiency of 25.9%; JOULE, Accepted.
Paolo Mariani
Post Doctoral Research Fellow
Department of Electronics Engineering
Via del Politecnico 1, IT-00133 Rome
Center for Hybrid and Organic Solar Energy (CHOSE)
Casale 11, Viale Pietro Gismondi s.n.c., IT-00133 Rome
University of Rome "Tor Vergata"
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Paolo Mariani obtained the Master Degree in Physics at the University of Rome "La Sapienza" by defending a thesis on "Phase transitions and stochastic transitions in finite systems with short and long-range interactions" (www.infn.it/thesis/PDF/getfile.php?filename=5804-Mariani-specialistica.pdf), under the supervision of prof. A. Giansanti. Statistical mechanics was the main research field with particular attention to molecular dynamics, implemented by computational simulations. Then, he has oriented his scientific interest in applied research by attending the second-level professional master's programmes in Photovoltaics Engineering at University of Rome “Tor Vergata”. In April 2012, Paolo Mariani defended a thesis on “Analysis and optimization of production process of DSSC photovoltaic devices”, under the supervision of prof. F. Giannini. By virtue of this experience, he started working at Dyepower Consortium, where he was involved in the development of large-area DSSC (Dye Sensitized Solar Cell), from October 2011 to December 2015. From May 2013 to April 2014, he was research fellow in the Electronic Engineering Department of University of Rome "Tor Vergata". Research program was the identification, deposition and optimization of materials for the production of DSSC photovoltaic panels. In April 2018, Paolo Mariani got Ph.D. in Electronic Engineering (University of Rome “Tor Vergata”) defending a thesis on “Novel classes of Dye Sensitized Solar Modules”, under the supervision of prof. Aldo Di Carlo. From July 2018, he is a research fellow (postdoctoral) in the Electronic Engineering Department of University "Tor Vergata" within the C.H.O.S.E. lab.
The research activity of Paolo Mariani is focused on the development of hybrid organic/inorganic large area solar cell. Currently, he is involved in the Graphene Flagship Project as research fellow (postdoctoral) under the supervision of Prof. Aldo Di Carlo (University of Rome Tor Vergata). Main topic is the study, the optimization and the characterization of Photovoltaic Modules Graphene/Perovskite. In particular, he studies both the replacement of metal counter-electrode in PSC (Perovskite Solar Cell) technology with carbon-graphene pastes and the overall encapsulation strategies. Moreover, he investigates the metallization process in order to realize metal grids for PSMs (Perovskite Solar Modules) also in the perspective of applying them in perovskite silicon tandem solar cell. All these explorations are based on original combination of GRMS (Graphene and Related Materials) ad hoc developed by IIT (Istituto Italiano di Tecnologia). He is also involved in the realization of Perovskite Photovoltaic‐Thermoelectric Hybrid Devices in collaboration with University of Milano Bicocca and with MIT. During his PhD, the activity has been focusing on the realization and characterization of novel classes of Dye-Sensitized Solar Modules (DSSMs) involving 2D materials or flexible substrates. Key words of him research are: "deposition techniques", "up-scaling", “large-area devices”, "2D materials" and "stability".
Luigi Angelo Castriotta
Post Doctoral Research Fellow
C.H.O.S.E. - c/o Casale 11
University of Rome "Tor Vergata"
Viale Pietro Gismondi s.n.c. - 00133 Rome - Italy
Tel. +39 0692949878
Mob. +39 3356316961
Mob. +39 3888138122
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Skype: luigi.a.castriotta
Linkedin: https://www.linkedin.com/in/luigi-angelo-castriotta-62125b72/
I am the Principal Investigator of EFESO, standing for "Exploiting Flexible pErovskites Solar technOlogies", a Global PostDoctoral Fellowship from Marie Skłodowska-Curie Actions, with the aim of exploiting perovskite solar technologies on flexible substrates, allowing to reduce costs and be adaptable to many surfaces. I am currently pursuing this project as a visiting Post Doctoral fellow at the University of North Carolina at Chapel Hill (USA), where I'm spending 21 months as part of the Outgoing Phase of the project.
I believe I have good communication skills obtained through all the different work and study experiences of my life.
I acquired good organizational skills during my University experience in Rome, Barcelona and in Dresden; the majority of the projects that have and had to be carried out in the Master in Nanoscience and Nanotechnology in Barcelona and in the Master in Organic and Molecular Electronics in Dresden were group projects of 3 or more people; a very good organization is fundamental to be able to carry out the work by the due date and continue studying.
During my PhD, I was part of the Innovative Training Network MAESTRO "MAking pErovskiteS TRuly explOitable", from Marie Skłodowska-Curie Actions, with the aim of fabricating perovskite solar technologies on larger areas; in this period, I acquired and experienced hard and soft skills on developing perovskite solar cells and modules, as well as interacting and collaborating with 17 partner university and companies around Europe. 7 different training events have been organized on different topics, from Intellectual Property, to hands-on session on how to fabricate solar cells. During this time, I also had the opportunity to work for Saule Technology, one of the first companies in Europe to commercialize perovskite technologies.
After my PhD, I got a Post Doctoral fellowship at University of Rome 'Tor Vergata' with the topic of Fabrication and characterization of large area perovskite solar modules for Silicon/Perovskite tandem configuration, in collaboration with ENEA. In this time, I was able to collaborate with Italian National agencies, experiencing also research topic on Silicon technologies.
I am convinced that the photovoltaics of tomorrow will be made of Hybrid and Organic materials, and I want to be part of this challenge!
I am the Principal Investigator of the Global Fellowship EFESO Grant agreement ID: 101068387 https://cordis.europa.eu/project/id/101068387
"EFESO, acronym of ""Exploiting Flexible pErovskites Solar technOlogies"" aims to bring perovskite technology on flexible substrates towards commercialization.
This project aims at upscaling stable Flexible Perovskite Solar Modules (FPSMs) by optimizing their fabrication process on flexible substrates, reducing inactive areas on modules, and by working on lead (Pb) trapping intrinsically, using doping and interface engineering, and extrinsically by encapsulation strategies.
The proposed project is divided into 3 main parts:
1. Materials: assessment of the flexible substrates, additives, and interface layers to get the best and stable layer to be used for device fabrication;
2. Device: fabrication and characterization of devices, focusing on lead trapping strategies by encapsulation and interface engineering;
3. Upscaling: optimization of the design and laser processes of P1-P2-P3 for indoor and outdoor applications (standard procedures to create a series connection of cells, to reduce losses encountered for large-area devices).
The principal objective of this action will be the fabrication of Flexible Perovskite Solar Cells with performances of 23% and 35% on small area devices at 1 Sun and 1000lx intensity respectively, FPSMs with power conversion efficiency (PCE) of 21% and 18% on an area greater than 10cm2 and 200cm2 respectively.
All devices fabricated will pass the ISOS D-L-T-1 tests and they will show a reduction of lead leakage by 4-5 orders of magnitude A final product demonstrator will be fabricated showing the applicability of these devices into the market.
The action will bring new materials, additives, sealants, polymers, solvent concentrations used to limit lead leakage, and build a stable and highly efficient device on a flexible substrate, from cell to module size. For these reasons, this action will grab the attention of the scientific community that will recognize this work as a potential path for prompt commercialization."
The updated publications of Luigi Angelo Castriotta are all available on Google Scholar at the following link:
https://scholar.google.com/citations?user=JWtGcZ4AAAAJ&hl=en&oi=ao
Below is the list:
Fabrication and morphological characterization of high-efficiency blade-coated perovskite solar modules
F Matteocci, L Vesce, FU Kosasih, LA Castriotta, S Cacovich, AL Palma, ...
ACS applied materials & interfaces 11 (28), 25195-25204 15 2019
Doping strategy for efficient and stable triple cation hybrid perovskite solar cells and module based on poly (3‐hexylthiophene) hole transport layer
N Yaghoobi Nia, E Lamanna, M Zendehdel, AL Palma, F Zurlo, LA Castriotta,...
Small 15 (49), 1904399 14 2019
Improved stability of inverted and flexible perovskite solar cells with carbon electrode
V Babu, R Fuentes Pineda, T Ahmad, AO Alvarez, LA Castriotta, ...
ACS Applied Energy Materials 3 (6), 5126-5134 5 2020
An Inter‐Laboratory Study on the Stability of All‐Printable HTM‐Free Perovskite Solar Cells
F De Rossi, J Barbé, DM Tanenbaum, L Cinà, LA Castriotta, V Stoichkov, ...
Energy Technology, n/a (n/a), 2000134. 4* 2020
Large area perovskite solar modules with improved efficiency and stability
S Pescetelli, A Agresti, S Razza, LA Castriotta, A Di Carlo
ISAECT 2019, Rome, November 27-29th 1 2019
Metal-semiconductor transition in thin film MAPbI3 perovskite
V Campanari, M Lucci, LA Castriotta, B Paci, A Generosi, M Guaragno, ...
Applied Physics Letters 117 (26), 261901 2020
Beyond 17% Stable Perovskite Solar Module via Polaron Arrangement of Tuned Polymeric Hole Transport Layer
NY Nia, M Zendehdel, M Abdi-Jalebi, LA Castriotta, FU Kosasih, ...
Nano Energy, 105685 2020
Upscaling Inverted Perovskite Solar Cells: Optimization of Laser Scribing for Highly Efficient Mini-Modules
F Di Giacomo, LA Castriotta, FU Kosasih, D Di Girolamo, C Ducati, ...
Micromachines 11 (12), 1127 2020
New Fullerene Derivative as an n‐Type Material for Highly Efficient, Flexible Perovskite Solar Cells of ap‐i‐n Configuration
T Ahmad, B Wilk, E Radicchi, R Fuentes Pineda, P Spinelli, J Herterich, LA Castriotta, ...
Advanced Functional Materials 30 (45), 2004357 2020
Semi-transparent triple cation Perovskite solar module exceeding 8% efficiency for BIPV applications
L Vesce, M Stefanelli, F Matteocci, LA Castriotta, E Lamanna, J Herterich, ...
2020 AEIT International Annual Conference (AEIT), 1-5 2020
Boosting Efficiency and Thermal stability of Large Area Perovskite Solar Modules Beyond 16.5%: The case of Polymeric and Small Molecule Hole Transport Layer
NY Nia, M Zendehdel, LA Castriotta, Z Zheng, A Di Carlo
NIPHO, Seville, February 23-25th 2020
Design, synthesis and application of new phenothiazine based Hole Transporting Materials (HTMs) for Perovskite Solar Cells (PSCs)
R Infantino, C Coppola, A Sinicropi, A Dessì, G Reginato, L Zani, A Mordini, LA Castriotta, ...
EnerChem20, Padova, February 12-14th 2020
Graphene and Perovskite: how GO alkaline doped 2D materials can boost the efficiency and stability of Perovskite Solar Cells using an upscaling route
LA Castriotta, A Agresti, S Pescetelli, M Stylianakis, E Kymakis, A Di Carlo
Graphene2019, Rome, June 25-29th 2019
Methyl Ammonium Free Perovskite Solar Cells: an out of Glove Box scalable route towards stability and efficiency
LA Castriotta, L Vesce, F Matteocci, M Stefanelli, D Di Girolamo, ...
HOPV 2019, Rome, May 12-15th 2019
Perovskite Solar Modules: Correlation Between Efficiency and Scalability
F Matteocci, LA Castriotta, AL Palma
Photoenergy and Thin Film Materials, 121-155 2019
Perovskite solar modules: a path to record-breaking devices
AL Palma, F Matteocci, L Vesce, LA Castriotta, NY Nia, E Calabrò, ...
EUPVSEC 2018, Brussels, September 24-28th 2018
Blade Coated Large Area Perovskite Solar Modules Exceeding 14.5% efficiency
LA Castriotta, L Vesce, F Matteocci, AL Palma, A Di Carlo
PSCO 2018, Lausanne, September 30th - October 2nd 2018
Blade and slot-die coated PEDOT:PSS for thermoelectric application
L La Notte, LA Castriotta, L Vesce, SA Castro-Hermosa, S Mardi, ...
Nano Innovation 2018, Rome, September 11-14th 2018
The effect of dryng for Perovskite Solar Cells to foster the upscaling and the lab to fab process
LA Castriotta, F Matteocci, L Vesce, L Cinà, A Di Carlo
Isophos-Maphebio 2017, September 3rd-7th 2017
Advanced Design and Electro-optical Characterization of Mesoscopic Solar Cells
LA Castriotta, L Cinà, S Mannsfeld
DOI: 10.13140/RG.2.2.24418.58563 2017
Claudio Ciceroni
Post Doctoral Research Fellow
C.H.O.S.E.
c/o Casale 11
University of Rome "Tor Vergata"
Viale Pietro Gismondi s.n.c. - 00133 Rome - Italy
Mobile: +393332464057
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Claudio Ciceroni obtained the Master Degree in Electronic Engineering (cum laude) at University of Rome "Tor Vergata". My thesis was on: "Design and realization of high frequency triodes with carbon nanotubes as cold cathodes" (Supervisor, Prof. Francesca Brunetti). Afterwards I attended the Ph.D. (fellowship holder) in Telecommunications and Microelectronics Engineering (XXVII cycle), within the OLAB (Optoelectonic and Nanoelectronic Devices) research group of the Electronics Engineering Department, at University of Rome "Tor Vergata". After one and half year as Scientific Staff member at Technische Univeristat of Munchen (TUM), now I am a Post-doctoral researcher in C.H.O.S.E. and the Lab-manager of the TEAM.
Claudio Ciceroni, PhD funded by the European FP7 project Go-Nexts, whose aim was the realization of hybrid-organic solar cells with graphene contacts and nanostructured design. The core of his research was the realization of carbon based semitransparent contacts, by CVD and spray deposition of CNTs, and the production of nanoimprinted organic solar cells, in order to obtain diffractive gratings optimized for light absorption. Currently working on the characterization of several thin-films and nanostructures of hybrid and organic materials by the mean of Scanning Probe Microscopy. Recently authored a book chapter concerning the use of graphene oxide in hybrid-organic solar cells.
Book chapters
1. Ciceroni C., Agresti A., Di Carlo A., Brunetti F. (2017). "Graphene Oxide for DSSC, OPV and Perovskite Stability". In Monica Lira-Cantu (Ed.) The Future of Semiconductor Oxides in Next-Generation Solar Cells (1st ed., pp.503-525)
Journal Articles
1. Ulisse, G., Ciceroni, C., Carlo, A.D., Brunetti, F., Jelenc, J., Muhammad, S., Varlec, A., Remskar, M., "Synthesis and field emission characteristics of W5O14 nanowires film", 2017, "Microelectronic Engineering #170", pp: 44 – 48,
DOI: 10.1016/j.mee.2016.12.026
2. Dianetti, M., Di Giacomo, F., Polino, G., Ciceroni, C., Liscio, A., D'Epifanio, A., Licoccia, S., Brown, T.M., Di Carlo, A., Brunetti, F., "TCO-free flexible organo metal trihalide perovskite planar-heterojunction solar cells", 2015, "Solar Energy Materials and Solar Cells #140", pp: 150 - 157,
DOI: 10.1016/j.solmat.2015.03.016
3. Ulisse, G., Brunetti, F., Ciceroni, C., Gemma, F., Dispenza, M., Fiorello, A.M., Ricci, F., Di Carlo, A., "A multifinger microtriode with carbon nanotubes field emission cathode operating at GHz frequency", 2015, "Nanotechnology #26", 5 pp,
DOI: 10.1088/0957-4484/26/21/215204
4. Susanna, G., Salamandra, L., Ciceroni, C., Mura, F., Brown, T.M., Reale, A., Rossi, M., Di Carlo, A., Brunetti, F., "8.7% Power conversion efficiency polymer solar cell realized with non-chlorinated solvents", 2015, "Solar Energy Materials and Solar Cells #134", pp: 194 - 198,
DOI: 10.1016/j.solmat.2014.11.042
5. LaNotte, L., Polino, G., Ciceroni, C., Brunetti, F., Brown, T.M., DiCarlo, A., Reale, A., "Spray-Coated Polymer Solar Cells based on Low-Band-Gap Donors Processed with ortho-Xylene", 2014, "Energy Technology #2", pp: 786 - 791,
DOI: 10.1002/ente.201402059
6. Ulisse, G., Ciceroni, C., Brunetti, F., Carlo, A.D., "Electrostatic beam focusing of carbon nanotubes electron source", 2014, "IEEE Transactions on Electron Devices #61", pp: 2558 - 2563",
DOI: 10.1109/TED.2014.2324171
Conference Papers
1. Schmidt, M., Lugli, P., Ulisse, G., Ciceroni, C., Brunetti, F., "Nanopatterning of P3HT:PCBM for organic solar cell realization", 2016, "IEEE-NANO 2015 - 15th International Conference on Nanotechnology", pp: 1366 - 1369,
DOI: 10.1109/NANO.2015.7388890
2. Ciceroni, C., Nia, N.Y., Ulisse, G., Di Carlo, A., Brunetti, F., "Anodized aluminum on transparent substrates as scaffold for perovskite growth", 2016, "IEEE-NANO 2015 - 15th International Conference on Nanotechnology", pp: 943 - 946,
DOI: 10.1109/NANO.2015.7388772
3. Ulisse, G., Ciceroni, C., Carlo, A.D., Brunetti, F., Jelenc, J., Varlec, A., Remskar, M., "Field emission from tungsten oxide nanowires W5O14 film", 2016, "IEEE-NANO 2015 - 15th International Conference on Nanotechnology", pp: 1190 - 1193,
DOI: 10.1109/NANO.2015.7388839
4. Ciceroni, C., Mincuzzi, G., Ulisse, G., Di Carlo, A., Brunetti, F., "Patterned carbon nanotubes semitransparent electrodes", 2014, "14th IEEE International Conference on Nanotechnology, IEEE-NANO 2014", pp: 698 - 701,
DOI: 10.1109/NANO.2014.6968130
5. Brunetti, F., Ulisse, G., Ciceroni, C., Ricci, F., Gemma, F., Dispenza, M., Fiorello, A.M., Di Carlo, A., "Field emission triode in a multifinger configuration with carbon nanotubes emitters", 2013, "Proceedings of the IEEE Conference on Nanotechnology", pp: 397 - 400,
DOI: 10.1109/NANO.2013.6720935
6. Ulisse, G., Ciceroni, C., Brunetti, F., Di Carlo, A., "Carbon nanotubes electron source", 2013, "14th IEEE International Vacuum Electronics Conference, IVEC 2013 - Proceedings", 2 pp,
DOI: 10.1109/IVEC.2013.6571065
7. Ciceroni, C., Ulisse, G., Brunetti, F., Di Carlo, A., "Study of the critical issues in the assembly of cold cathodes in electron gun for vacuum tube", 2013, "UCMMT 2013 - 2013 6th UK, Europe, China Millimeter Waves and THz Technology Workshop", 2 pp,
DOI: 10.1109/UCMMT.2013.6641533
8. Brunetti, F., Ulisse, G., Ciceroni, C., Di Carlo, A., Tamburri, E., Gugliemotti, V., Terranova, M.L., "Field emission behaviour of nickel nanowires grown by electrochemical deposition", 2009, "2009 9th IEEE Conference on Nanotechnology, IEEE NANO 2009", pp: 160 - 162, Electronic ISBN: 978-981-08-3694-8
Jessica Barichello
Post Doctoral Research Fellow
C.H.O.S.E.
c/o Casale 11
University of Rome "Tor Vergata"
Viale Pietro Gismondi s.n.c. - 00133 Rome - Italy
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Jessica Barichello is a post-doctoral researcher at CHOSE (Centre for Hybrid and Organic Solar Energy, Department of Electronic Engineering, University of Rome ‘‘Tor Vergata’’). In 2019, Jessica obtained a PhD in Environmental Science, title of the thesis ‘From Dye Sensitized to Perovskite Solar Cells: processes and materials for the forthcoming era of Photovoltaic Technology’ at Ca’ Foscari University of Venice, Italy. She had experiences in DSSC and Perovskite Solar Cells fields. At the moment, she is working as a post doc in the European project City Solar on semi-transparent perovskite solar cells.
Jessica Barichello's research activity concerns the development and characterization of perovskite solar cell for BIPV applications (UE –HORIZON 2020 – CitySolar). Her research focus on the scaling-up of a low temperature manufacturing process developing semi-transparent perovskite solar devices. Mainly, she is working on bromine and chlorine based perovskites using the blade coating deposition technique.
L. Borella, L. Vesce, P. Mariani, J. Barichello, A. Di Carlo, N. Trivellin, E. Sforza. Spectral Changes by Dye Sensitized Solar Modules Influence the Pigment Composition and Productivity of Arthrospira maxima and Increase the Overall Energy Efficiency. Adv. Sustainable Syst. 2022, 2100346. DOI: 10.1002/adsu.202100346
J. Barichello, P. Mariani, F. Matteocci, L. Vesce, A. Reale, A. Di Carlo, M. Lanza, G. Di Marco, S. Polizzi, G. Calogero. The Golden Fig: A Plasmonic Effect Study of Organic-Based Solar Cells. Nanomaterials 2022, 12, 267. DOI: 10.3390/nano12020267
J. Barichello, L. Vesce, P. Mariani, E. Leonardi, R. Braglia, A. Di Carlo, A. Canini, A. Reale. Stable Semi-Transparent Dye-Sensitized Solar Modules and Panels for Greenhouse Application. Energies 2021, 14, 6393. https://doi.org/10.3390/en14196393
E. Calabrò, F. Matteocci, B. Paci, L. Cina, L. Vesce, J. Barichello, A. Generosi, A. Reale, A. Di Carlo. Easy strategy to enhance thermal stability of planar PSCs by perovskite defect passivation and low-temperature carbon-based electrode. ACS Appl. Mater. Interfaces 2020, 12, 29, 32536–32547
J. Barichello, L. Vesce, F. Matteocci, E. Lamanna, A. Di Carlo. The effect of water in Carbon-Perovskite Solar Cells with optimized alumina spacer. Solar Energy Materials and Solar Cells, 197, (2019), 76–83
Calogero, G.; Barichello, J.; Citro, I.; Mariani, P.; Vesce, L.; Bartolotta, A.; di Carlo, A.; di Marco, G. Photoelectrochemical and spectrophotometric studies on dye-sensitized solar cells (DSCs) and stable modules (DSCMs) based on natural apocarotenoids pigments. Dye. Pigment. 2018, 155, 75–83
S. Armeli Minicante, E. Ambrosi, M. Back, J. Barichello, E. Cataruzza, F. Gonella, E. Trave. Development for an eco-protocol for seaweed chloophyll extraction and possible application on Dye Sensitized Solar Cells. Journal of Physics D: Applied Physics 49 (2016) 295601 (7pp).
Francineide Lopes de Araújo
Post Doctoral Research Fellow
C.H.O.S.E.
c/o Casale 11
University of Rome "Tor Vergata"
Viale Pietro Gismondi s.n.c. - 00133 Rome - Italy
Modile:+39 3488449408
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Francineide Lopes de Araújo graduated in Physics from the Uberlândia Federal University in 2012. She received her MS degree in Materials Science and Engineering in 2014 from the São Carlos School of Engineering at the University of São Paulo (EESC/USP), where she studied optical and structural properties of polyfluorenes through ultrathin films and single-molecule spectroscopy. She received her PhD in Applied Physics in 2018 from the São Carlos Institute of Physics at the University of São Paulo (IFSC/USP), where she acted in organic electronics, specifically in the fabrication and electrical characterization of organic solar cells (OPVs). Currently, she serves as a postdoc at the Institute of Chemistry, University of Campinas, in the Laboratório de Nanotecnologia e Energia Solar (LNES), under the supervision of Prof. Dr. Ana Flávia Nogueira. Recently, she is a visiting researcher at CHOSE until October 2023, focusing on the fabrication and characterization of perovskite solar cells. Research Supported by FAPESP/Scholarships abroad – Research Internship – Post-doc (Grant number: 22/07847-8).
Francineide Lopes de Araújo's research activity concerns applying graphene materials and 2D perovskite as intra and interlayers in perovskite solar modules (PSMs) using the interface engineering method. These modifications are expected to reduce surface defects, minimize the interfacial recombination and, at the same time, promote fast charge extraction, resulting in PSMs with high performance and stability. From the point of view of processing and cost, the versatility of these materials (graphene and 2D perovskites) in terms of processability and low cost is a beneficial and indispensable characteristic for the expansion and commercialization of PSMs.
1. Szostak, R.; Gonçalves, A. S.; Freitas, J. N.; Marchezi, P. E.; Araújo, F. L.; Schelhas, L. T.; Tolentino, H. C. N.; Toney, M. T.; Marques, F. C.*; Nogueira, A. F. In situ and operando characterizations of metal halide perovskite and solar cells: Insights from lab-sized devices to upscaling processes. Chemical Reviews, 123 (6), 3160-3236, 2023. https://doi.org/10.1021/acs.chemrev.2c00382
2. Paula, Kelly T.; Santos, Sabrina N. C.; Facure, Murilo H. M.; Araujo, Francineide L.; Andrade, Marcelo M. B.; Correa, Daniel S.; Mendonça, Cleber R. Fabrication of interdigitated electrodes of graphene oxide/silica by femtosecond laser-induced forward transfer for sensing applications. Journal of Applied Physics, v.133, p.053103, 2023.
https://doi.org/10.1063/5.0137926
3. De Araújo, Francineide; Nogueira, Ana; De Freitas, Jilian. Facile Methods for the Assembly of Large-Area Perovskite Solar Cells and Mini-Module: A Step-by-Step Description of Layers Processing. Journal of the Brazilian Chemical Society, Vol. 34, No. 6, 794-808, 2023.
https://dx.doi.org/10.21577/0103-5053.20220148
4. Custódio Mota, Isabela; Pedroso Silva Santos, Bianca; Értola Pereira Dos Santos, Raphael; Banar Guedes, Luísa; Tenório Soares, Igor; Rubio Arias, Jose Jonathan; Lopes De Araújo, Francineide; Nogueira, Ana Flávia; Vieira Marques, Maria De Fátima. Influence of reaction time on properties of regioregular poly(3-hexylthiophene) by the Grignard metathesis polymerization. Journal of Thermal Analysis and Calorimetry, v.147, p.5037 - 5048, 2022.
https://doi.org/10.1007/s10973-021-10890-4
5. Scalon, Lucas; Szostak, Rodrigo; Araújo, Francineide L.; Adriani, Karla F.; Silveira, Julian F. R. V.; Oliveira, Willian X. C.; Da Silva, Juarez L. F.; Oliveira, Caio C.; Nogueira, Ana Flávia. Improving the Stability and Efficiency of Perovskite Solar Cells by a Bidentate Anilinium Salt. JACS Au. , v.2, p.1233 - 1503, 2022.
https://doi.org/10.1021/jacsau.2c00151
6. Moral, Raphael; Hermsdorff, Alden; Marchezi, Paulo; Germino, José; Bonato, Luiz; De Araújo, Francineide; Nogueira, Ana. Addition of N-(2-Aminoethyl)naphthalimide and Mercaptopropionic Acid to Increase the Stability of CsFAMA Perovskite Solar Cells. Journal of the Brazilian Chemical Society, v.33, p.973 - 983, 2022.
https://doi.org/10.21577/0103-5053.20220072
7. Neto, Alfredo Leithold; Scalon, Lucas; Octavio De Araujo, Luis; Lopes De Araújo, Francineide; Spada, Edna Regina; Pereira Da Cunha, Mariana Richelle; Desordi, Jaqueline Cristine; Barreto, Rafael Carvalho; Macedo, Andreia Gerniski; Faria, Roberto Mendonça; Rodrigues, Paula Cristina. New insights into DPP3Th and C70 based planar solar cells: a study combining DFT and experimental approach. Materials Chemistry and Physics., v.262, p.124271, 2021. https://doi.org/10.1016/j.matchemphys.2021.124271
8. Marchezi, Paulo Ernesto; De Araújo, Francineide Lopes; Szostack, Rodrigo; Germino, José Carlos; Therézio, Eralci M.; Marletta, Alexandre; Nogueira, Ana Flavia. Reduced graphene oxide in perovskite solar cells: the influence on film formation, photophysics, performance, and stability. Journal of Materials Chemistry C, v.9, p.14648-14658, 2021. https://doi.org/10.1039/D1TC01360B
9. Santos, Bianca Pedroso S.; Correa, Roger S.; Veiga, Amanda G.; Péan, Emmanuel V.; Borges, Bruno G.A.L.; Araújo, Francineide L.; Ribeiro, Arthur C.; Furtado, José G.M.; Davies, Matthew L.; Nogueira, Ana F.; Rocco, Maria L.M.; Marques, Maria F.V. Statistical and block conjugated polymers for bulk heterojunction solar cells: Molecular orientation, charge transfer dynamics and device performance. Materials Science and Engineering B-Advanced Functional Solid-State Materials, v.270, p.115225, 2021.
https://doi.org/10.1016/j.mseb.2021.115225
10. Marchezi, P. E.; Araújo, F. L.; Machado, E. G.; Goncalves, A. S.; Nogueira, A. F. Desafios e oportunidades para o desenvolvimento de células solares fotovoltaicas emergentes. ComCiência (UNICAMP), v.223, p.1, 2021.
11. Santos, Bianca Pedroso Silva; Lima, Allan Bastos; De Araújo, Francineide Lopes; Mota, Isabela Custódio; Ribeiro, Arthur De Castro; Nogueira, Ana Flávia; Furtado, José Geraldo De Melo; Garcia Filho, Fabio Da Costa; Marques, Maria De Fátima Vieira; Monteiro, Sergio Neve. Synthesis of novel low bandgap random and block terpolymers with improved performance in organic solar cells. Journal of Materials Research and Technology-JMR&T, v.10, p.51 - 65, 2021. https://doi.org/10.1016/j.jmrt.2020.11.101
12. Araújo, F.L.; Amorim, D.R.B.; Torres, B.B.M; Coutinho, D.J.; Faria, R.M. Electrical performance of PTB7-Th:PC71BM solar cell when in contact with the environment. Solar Energy, v.208, p.583 - 590, 2020.
https://doi.org/10.1016/j.solener.2020.08.005
13. Germino, José Carlos; Szostak, Rodrigo; Motti, Silvia G.; Moral, Raphael F.; Marchezi, Paulo E.; Seleghini, Heitor S.; Bonato, Luiz G.; De Araújo, Francineide Lopes; Atvars, Teresa D. Z.; Herz, Laura M.; Fenning, David; Hagfeldt, Anders; Nogueira, Ana Flávia. Postpassivation of Multication Perovskite with Rubidium Butyrate. ACS Photonics, v.7, p.2282 - 2291, 2020.
https://doi.org/10.1021/acsphotonics.0c00878
14. De Castro Sousa, Lívia Maria; Da Silva Miranda, Guilherme; De Araújo, Francineide Lopes; Torres, Bruno Bassi Millan; Faria, Roberto Mendonça; Balogh, Debora Terezia. Bulk-heterojunction polymer photovoltaic cells manufactured using non-halogenated and non-aromatic solvent. Journal of Materials Science-Materials in Electronics, v.31, p.6927 - 6936, 2020.
https://doi.org/10.1007/s10854-020-03256-3
15. De Araújo, Francineide Lopes; Da Silva, Jeann Carlos; Szostak, Rodrigo; Marchezi, Paulo Ernesto; Moral, Raphael Fernando; De Freitas, Jilian Nei; Nogueira, Ana Flávia. Effect of the incorporation of poly(ethylene oxide) copolymer on the stability of perovskite solar cells. Journal of Materials Chemistry C, v.8, p.9697 - 9706, 2020. https://doi.org/10.1039/D0TC02078H
16. Paula, Kelly T.; Santos, Molíria V.; Facure, Murilo H.M.; Andrade, Marcelo B.; Araújo, Francineide L.; Correa, Daniel S.; Ribeiro, Sidney J.L.; Mendonça, Cleber R. Laser patterning and induced reduction of graphene oxide functionalized silk fibroin. Optical Materials, v.99, p.109540, 2020.
https://doi.org/10.1016/j.optmat.2019.109540
17. Araújo, F. L.; Amorim, D. R. B.; Coutinho, D. J.; Faria, R. M. Effects of air exposition on series and shunt resistances of a solar cell based on PTB7-Th:PC71BM. Journal of Materials Science-Materials in Electronics, v.30, p.16806 - 16811, 2019.
https://doi.org/10.1007/s10854-019-01343-8
18. Araújo, F.L.; Amorim, D.R.B.; Torres, B.B.M; Coutinho, D.J.; Faria, R.M. Effects of additive-solvents on the mobility and recombination of a solar cell based on PTB7-Th:PC71BM. Solar Energy, v.177, p.284-292, 2019.
https://doi.org/10.1016/j.solener.2018.11.027
19. Araújo, F L; Valente, G T; Faria, R M; Guimarães, F E G. How surface interactions freeze polymer molecules at room temperature: a single molecule approach. Iop Conference Series: Materials Science and Engineering, v.97, p.012003, 2015.
https://doi:10.1088/1757-899X/97/1/012003
The 19th edition of the International School on Hybrid and Organic Photovoltaics (ISOPHOS®) will be held from the 2nd till 6th of September 2019 in the wonderful atmosphere of Castiglione della Pescaia (Italy)
CHOSE e discoverplaces.travel insieme per far scoprire le bellezze dei nostri territori.
CHOSE organizza in collaborazione con l'Università degli Studi di Roma Tor Vergata e l'associazione FREEnergy un Master di II livello in "Ingegneria del Fotovoltaico" .
On the importance of ferroelectric domains for the performance of perovskite solar cells
The effect of ferroelectric polarization patterns in MAPbI3 on JV characteristics has been analyzed. We discuss models for the polarization orientation pattern and magnitude of the ferroelectric domains. Simulations performed on real patterns show that the presence of ordered ferroelectric domains, even with a weak characteristic polarization magnitude enhances the power conversion efficiencies and are mandatory to reproduce the experimental J-V characteristics.
A Crystal Engineering approach for perovskite solar cells and modules fabrication out of the glove box
we fabricated high efficiency perovskite solar cells (PSC) and perovskite solar modules (PSM) utilizing several Hole Transport Layers (HTLs). The results show that the Crystal Engineering approach remarkably improved the device performance reaching a power conversion efficiency of 17%, 16.8% and 7% for spiro-OMeTAD, P3HT and HTL free, respectively.
Fully-sprayed flexible polymer solar cells with a cellulose-graphene electrode
Light, flexible and low-cost organic solar cells made entirely by spray and with an innovative cellulose and graphene-based electrode! The work, in collaboration with the Smart Materials group of the ISTITUTO ITALIANO DI TECNOLOGIA has been published on the important magazine "Materials Today Energy".
Highly efficient perovskite solar cells for light harvesting under indoor illumination via solution processed sno2/mgo composite electron transport layers
A new architectures in CH3NH3PbI3 based planar perovskite solar cells incorporating solution processed SnO2/MgO composite electron transport layers that show the highest power outputs ever reported under typical 200–400 lx indoor illumination conditions.
Perovskite solar cells on paper and the role of substrates and electrodes on performance
The first perovskite solar cell (PSC) fabricated directly on a paper substrate with a maximum power conversion efficiency of 2.7% is here reported.
Photoelectrochemical and spectrophotometric studies on dye-sensitized solar cells (dscs) and stable modules (dscms) based on natural apocarotenoids pigments
We present a study on dye-sensitized solar cells (DSCs) and we fabricate dye-sensitized solar modules (DSCMs) based on natural apocarotenoids extracted from the achiote's seeds (annatto). Use of less polar solvent such as diethyl ether improves the bixin concentration in the annatto extract which, was employed as sensitizer in the devices.
Fully laser processed Perovskite Solar Cell modules with 95% Aperture Ratio
Laser patterning has been applied to realize Perovskite solar modules with a ratio between active and total substrate area of 95% and an efficiency of 9.3%. These values are new records for large area (14.5 cm2) fully laser processed perovskite devices. This work signs a forward step to the industrialization of perovskite based solar technology. Results have been published on IEEE Journal of Photovoltaics DOI: 10.1109/JPHOTOV.2017.2732223
Graphene-Perovskite Solar module with efficiency 12.6% on 50 cm2
Graphene interface engineering (GIE) is proposed as an effective way to boost efficiency in Perovskite solar cells and modules.
A record efficiency of 12.6% on 50 cm2 module active area has been achieved by introduce Graphene in the mesoporous TiO2
and lithium neutralized graphene oxide (GO-Li) at the mTiO2/perovskite.
Results have been published on ACS Energy Lett. 2017, 2, 279−287
Reduced Graphene Oxide as Efficient and Stable Hole Transporting Material in Mesoscopic Perovskite Solar Cells
Nano Energy
DOI: 10.1016/j.nanoen.2016.02.027
We fabricated the first perovskite-based monolithic series-type module showing very promising results in terms of the power conversion efficiency, the reproducibility of the fabrication process and long-term stability.
We fabricated perovskite based solar cells using CH3NH3PbI3-xClx with different hole transporting materials such as Spiro-OMeTAD and P3HT.
We fabricated the first solid state dye solar cell (SDSC) module using poly(3-hexilthiophene) (P3HT) as Hole Transport Material for the dye regeneration process.
Fully sprayed polymer solar cell modules open the way to bring Photovoltaics nominally everywhere, thanks to spray coating conformability to virtually any kind of substrate.
We have demonstrated the feasibility of the fabrication of a photovoltaic greenhouse roof by using techniques based on solution processing (spray coating and screen printing).